Functional Principle

 

Functional Principle

  • When we started the development of AMESA we selected a modified cooled probe method acc. EN-1948, which complies more to the US EPA method 23A. In our opinion this method is the most practical method for long-term sampling of dioxins. The other methods (cooled probe, filter-cooler) produces condensate which has to be collected and analysed.
    By using the dilution method there exists a higher risk of dioxin deposits inside the probe, because of the dry process. Contrary to the cooled probe method by the dilution method exists no self-cleaning effect due to the condensation of the flue gas humidity inside the probe.
    According US EPA method 23A the collected condensate does not need to be analysed, because it is well known that the amount of dioxins in the condensate is negligible. This was confirmed with AMESA in a lot of measurements in which the condensate was collected and analysed separately.

    The functional principle of the sampling is as follows:

    • Extraction of a volume stream constantly and isokinetically from flue gas
    • The dioxins and furans (PCDD/PCDF) are collected in the adsorption cartridge over a variable period
      between 6 hours and 4 weeks.
    • Identification of non-usual operating conditions like e.g. high O2-value in flue gas, and stop of
      measurement if necessary
    • To determine the quantity of the collected dioxins and furans the cartridge and the SRAM memory card
      has to be analysed by a laboratory which is familiar with the analysis of PCDD/PCDF-adsorber cartridges




    A Cooled (< 70 °C) titanium probe for isokinetic extraction of a volume stream.

    B Measurement stream and condensate are drawn through the cartridge filled with adsorber resin
       (quartz wool as a prefilter).

    C Measurement stream and condensate are drawn through the measuring gas line to the control cabinet.

    D Control cabinet with separation of the condensate by cooling (< 5 °C) and infinitely variable control of the
       isokinetical extraction.

    E User-friendly operation of AMESA by menu dialogue in process controller. Data input for plant specific
       parameters and operation by means of keyboard and LCD-monitor. Analysis of the emission values by
       means of SRAM memory chip and analysis results.

    F Compressed air, power supply and input signal conduits.

    G Condensate drain and flue gas recycling

    H Signal output (optional)

    I  Coolant connection (if TFluegas > 70 °C)